Features of the photoconductivity of the quasi-one-dimensional compound TiS3

Problem formulating. The features of linear and nonlinear conductivity, magnetic conductivity, thermopower, and the Hall effect observed on TiS3 whiskers indicate phase transitions to a state of CDW in this compound, but there is no direct evidence yet. The study of photoconductivity would allow us to learn more about the nature of these phase transitions.

Goal. Study of the effect of radiation in the range from near-IR to near-UV on the conductivity of single-crystal TiS3 whiskers at 4.2 <T<300 K and search for features of photoconductivity in the temperature range of the suggested phase transitions. Result. Features of the photoconductivity of TiS3 at temperatures of 50 K and 15 K, at which the −dlnσ/d(1/T) maxima were previously observed, are found. A decrease in photoconductivity at these temperatures indicates a change in the electronic spectrum, which may be associated with the formation of CDW. 

Practical meaning. In the case of developing TiS3-based photosensors, it is important to study the photoconductivity in a wide temperature range.