350 rub
Journal Nanotechnology : the development , application - XXI Century №1 for 2010 г.
Article in number:
Carbyne - the Third Allotrope form of Nanocarbon
Keywords: carbon allotrope forms &#945 -carbine &#946 -carbyne polyyne cumulene diamond graphite
Authors:
Kudryavtsev Yu.P., Babaev V.G., Guseva M.B., Khvostov V.V., Savchenko N.F., Alexandrov A.F.
Abstract:
Basing on electron diffraction data, electron and oscillation spectroscopy the existence of the third allotrope modification of line-chain carbon based on sp1-bond is stated and its structure model is described. Particular attention is paid to the IR- and Raman spectra of carbyne. This allotrope modification is unstable in macrosystem, but gets stability in nanosize area. Synthesized and found in nature samples of carbyne do not exceed 100 nm.
Pages: 37-52
References
  1. Kudryavtsev Yu.P., Euvsyukov S., Guseva M. et al. Chemistry and Physics of Carbon, A series of Advances, Ed. by Peter A. Thrower, New York: Marcel Dekker, Inc. 1997. V. 25. P. 1-69.
  2. Мастеров В.Ф. Физические свойства фуллеренов // Cоросовский образовательный журнал 1997. № 1. 92 .
  3. Haddon R.C. Phil. Trans. Roy. Soc. London, Ser. APhys. Sci. Eng. 1993. 343, 53
  4. Diederich F. and Rubin Y. Science. 1989. 245.P.1088.
  5. Rubin Y, Diederich F.// J.Am.Chem.Soc. 1990. 112.P.1607.
  6. Rubin Y, M.Kahr, Diederich F.// J.Am.Chem.Soc. 1991. 113.P.495.
  7. Glaser C.// Ann.Chem. 1970. Bd.154.P.137 - 171.
  8. Сладков А.М. Полисопряженные полимеры. М.: Наука. 1989. С. 254.
  9. Khvostov V.V., Guseva M.B., Babaev V.G. et al. Auger-spectroscopy studies of amorphous carbon film. Surf.Sci.Lett. 1986. V. 169. No. 2. P. 1253-1258.
  10. Heimann R.B., Kleiman J.I., Salansky N.M. Carbon. 1984. 22. 147
  11. Heimann R.B., Kleiman J.I., Salansky N.M. // Nature Lett.1983. 306. 164.
  12. Гусева М.Б., Бабаев В.Г., Бабина В.М. и др.Письма в ЖЭТФ // 1995. Т. 62. С. 698.
  13. Lannoo М., Friedel Р.Atomic and Electronic Structure of Surfaces Ser. in Surface Sciences, Berlin-Heideiberg: Springer-Verlag. 1991. V. 16. P. 255.
  14. Raghavachari K., Binkley J.S. // J. Chem. Phys. 1999. V. 87. P. 2191.
  15. Kastner J., Kuzmany H., Kavan L. et al. Macromolecules. 1995. V. 28. P. 344.
  16. Weltner W., McLeod D.J.Chem. Phys. 1966. V. 45. P. 3096.
  17. Спицина Н.Г., Бойко Г.Н., Кудрявцев Ю.П. и др. // Изв. АН. Сер. хим. 1995. Т. 44. № 7. С. 1387.
  18. Babaev V.G., Guseva M.B. Heimann R., Evsyukov S.E. Car-
    byne and Carbynoid Stractures, Kluver Academic Publishers, Physics and Chemistry of Materials with Low-Dimensional Structures / Ed. by L. Kavan. 2000. V. 21. P. 159
  19. Кудрявцев Ю.П., Евсюков С.Е. и др. Изв. АН СССР. Сер. хим. 1993. № 3. С. 450.
  20. Бердюгин В.В., Кудрявцев Ю.П., Евсюков С.Е. и др. // ДАН СССР. 1989. Т. 305. С. 36244.
  21. Knight D.S., White W.B. // J. Mater. Res. 1989. V. 4. P. 385.
  22. Коршак ВВ., Кудрявцев Ю.П, Евсюков С.Е. и др. // ДАН СССР. 1988. Т. 298. С. 1421.
  23. Miller F.A., Matsubara F.A. // Spectrochimica Acta. 1966. V. 22. P. 173.
  24. Miyano K., Maeda T. // Phys. Rev. B. 1986.
  25. Kijima M., Sakai Y. and Shirakawa H. // Synth. Metals. 1995. V. 71. P. 1837.
  26. Ohmura K., Kijima M., Shirakava H. // Synth. Metals. 1997. V. 84. P. 417.
  27. Kavan L, Kastner J.Carbon. 1994.V. 32.P. 1533.
  28. Lagow R., Kampa J.J. et al. Science. 1995. V. 267. P. 362.
  29. Chupka WA., Inghram M.G. // J. Phys. Chem. 1955. V. 59. P. 100.
  30. Pitzer K.S., Clementi E. J. // Amer. Chem. Soc. 1959. V. 81. № 17. P. 4477.
  31. Drowart J., Bowrns R.P., Marie G.De. et al. // J. Chem. Phys. 1959. V. 31. P. 1131.
  32. Kleiman J.L., Heiman R.B., Hawken D. et al. // J. Appl. Phys. 1984. V. 56. P. 1440.
  33. Бабаев В.Г., Гусева М.Б., Жук А.З. и др. // ДАН. 1995.
    Т. 40. № 7. С. 323.
  34. Ravagnan L., Siviero F., Lenardi C. et al. // Phys. Rev. Letter. 2002. V. 89. P. 28.
  35. Togaya M. // Chem. Phys. 1999. V. 110. P. 441.
  36. Weiqi Luo, M.S.Atomistic materials modeling of complex systems: carbynes, carbon nanotube devices and bulk metallic glasses. PHD dissertation. The Ohio State University. 2008.