350 rub
Journal №2 for 2013 г.
Article in number:
About the influence of stationary and electron beam heating on electrophysical characteristics nanoscaled sol-gel alumina films
Authors:
E.V. Lugovoy, S.P. Avdeev, P.V. Serba, M.V. Rubashkina, V.V. Tkachuk
Abstract:
The article comprises the features of the influence of the stationary and the local thermal effects in vacuum formed on the electrical characteristics of sol-gel films on the basis of aluminum oxide on silicon substrates. As a film-forming basis it is selected aluminum isopropoxide, which allows obtaining high purity boehmite xerogel. The formation of Al2O3 is indicated by ellipsometry and X-ray photoelectron spectroscopy on films synthesized by sol-gel method and formed by thermal vacuum annealing by electron beam treatment. It is determined that the effective value of roughness of synthesized films decreases from 1,1 to 0,5 nm with increasing the annealing temperature from 200 to 1000 °C. This allows producing of high-quality epitaxial structures of alumina on the surfaces of formed films.It is considered that dielectric conductivity of sol-gel films after annealing in vacuo at 23 ... 26 % is smaller than the dielectric constant of single crystal of sapphire.
Pages: 30-35
References

  1. Ruppi S., Larsson A. Chemical vapour deposition of k-Al2O3 // Thin Solid Films. 2001. № 388. P. 50-61.
  2. Siddhartha K. Pradhan, Philip J. Reucroft, Yeonkyu K. Crystallinity of Al2O3 films deposited by metalorganic chemical vapor deposition // Surface and Coatings Technology. 2004. № 176. P. 382-384.
  3. / Nobuyuki Kawakami, Yoshihiro Yokota, Takeshi Tachibana, Kazushi Hayashi. Atomic layer deposition of Al2O3 thin films on diamond // Diamond & Related Materials. 2005. № 14. P. 2015-2018.
  4. Yadong Zhang, Jacob A. Bertrand, Ronggui Yang, et al. Electroplating to visualize defects in Al2O3 thin films grown using atomic layer deposition // Thin Solid Films. 2009. № 517. P. 3269-3272.
  5. Gottmann J., Kreutz E.W. Pulse laser deposition of alumina and zirconia thin films on polymers and glass as optical and protective coating // Surface and Coating Technology. 1999. № 116-119. P. 1189-1194.
  6. Chengbin Jing, Xiujian Zhao, Yongheng Zhang Sol-gel fabrication of compact, crack-free alumina film // Materials Research Bulletin. 2007. № 42. P. 600-608.
  7. Masalski J., Gluszek J., Zabrzeski J., et al. Improvement in corrosion resistance of the 316l stainless steel by means of Al2O3 coatings deposited by the sol-gel method // Thin Solid Films. 1999. № 349. P. 186-190.
  8. Avdeev S.P., Mileshko L.P., Muzy'kov P.G. i dr. Perspektivy' primeneniya e'lektronno-luchevoj obrabotki dlya modifikaczii zol'-gel'ny'x plenok legirovannogo dioksida kremniya // Fizika i ximiya obrabotki materialov. 1998. № 2. S. 77-83.
  9. Loxov, Sapogin, Cherednichenko. Zaryadovy'e proczessy' pri e'lektronno-luchevoj modifikaczii poverxnosti opticheskix stekol // Izv. VSh Severo Kavkazskij region. Estestvenny'e nauki. 1995. № 3. S. 62-67.
  10. Psheniczy'n V.I., Abaev M.I, Ly'zlov N.Ju. E'llipsometriya v fiziko-ximicheskix issledovaniyax. L.: Ximiya. 1986. 152 s.
  11. Analiz poverxnosti metodami ozhe- i rentgenovskoj fotoe'lektronnoj spektroskopii: Per. s angl. / Pod red. D. Briggsa, M.P. Sixa. M.: Mir. 1987. 600 s.