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Journal Biomedical Radioelectronics №12 for 2014 г.
Article in number:
Mathematical model of interaction of carbonaceous fullerene containing mineral shungite and microporous crystalline aluminosilicate mineral zeolite with water
Keywords: shungite zeolite nanostructure fullerens water TEM NES DNES
Authors:
Ignat Ignatov - Sc.D., Professor, Scientific Research Center of Medical Biophysics (SRCMB) (Sofia, Bulgaria). E-mail: mbioph@dir.bg
O.V. Mosin - Ph.D. (Chem.), Research Scientist, Moscow State University of Applied Biotechnology. E-mail: mosin-oleg@yandex.ru
Abstract:
We studied the mathematical nmodel of interaction of amorphous, uncrystallized, fullerene analogous carbon containing natural mineral shungite from Zazhoginskoe deposit in Karelia (Russian Federation) and microporous crystalline aluminosilicate mineral zeolite (Most, Bulgaria) with water. There are submitted data about the nanostructure, obtained with using of transmission electron microscopy (TEM-method), IR-spectroscopy (NES and DNES-method), as well as composition, physical chemical, and biological properties of these minerals. The average energy (∆EH...O) of hydrogen Н-O-bonds among individual molecules H2O after treatment of shungite and zeolite with water is measured at -0,1137 eV for shungite and - 0,1174 eV for zeolite. The calculation of ∆EH...O for shungite with using DNES method compiles 0,0025±0,0011 eV and for zeolite -1,2±0,0011 eV. This result suggests the restructuring of ∆EH...O values among H2O molecules with a statistically reliable increase of local maximums in DNES-spectra. Also are demonstrated the prospects of using shungite, possessing high absorption, catalytic and bactericidal activity, as an adsorbent in water-treatment, water purification, and other industries.
Pages: 23-31
References

  1. Khavari-Khorasani G., Murchison D.G. The nature of carbonaceous matter in the Karelian shungite // Chem. Geol. 1979. V. 26. P. 165-82.
  2. Volkova I.B., Bogdanov M.V. // Petrology and genesis of the Karelian shungite-high rank coal // Int. J. Coal Geol. 1986. V. 6. P. 369-79.
  3. Panayotova M., Velikov B. Kinetics of heavy metal ions removal by use of natural zeolite // Journal of Environmental Science and Health. 2002. V. 37. № 2. P. 139-147.
  4. Parfen-eva L.S. Electrical conductivity of shungite carbon // Solid State Physics. 1994. V. 36. № 1. P. 234-236.
  5. Kasatochkin V.I., Yurkovsky I.M., Samoilov V.S. Submikroporous structure of shungites // Solid Fuel Chemistry. 1978. № 3. P. 17-21.
  6. Khadartsev A.A., Tuktamyshev I.S. Shungites in medical technologies // Vestnik Novih Medicinskih Technologii. 2002. V. 9. № 2. P. 83-86 [in Russian].
  7. Kovalevski V.V. Structure of shungite carbon // Natural Graphitization Chemistry. 1994. V. 39. P. 28-32.
  8. Mosin O.V., Ignatov I. Cmposition and structural properties of fullerene analogous mineral shungate // Journal of Nano and Microsyctem Technique. 2013. V. 1. P. 32-40 [in Russian].
  9. Golubev E.A. Local supramolecular structures shungite carbon / in Proceedings of the Int. Symp. "Carbon-formation in geological history" // Petrozavodsk: Publishing House of the Karelian Research Center, Russian Academy of Sciences. 2000. P. 106-110 [in Russian].
  10. Kovalevski V.V., Buseckb P.R., Cowley J.M. Comparison of carbon in shungite rocks to other natural carbons: an X-ray and TEM study // Carbon. 2001. V. 39. P. 243-256.
  11. Jushkin N.P. Globular supramolecular structure shungite: data scanning tunneling microscopy // Reports. Acad. Science USSR. 1994. V. 337. № 6. P. 800-803 [in Russian].
  12. Reznikov V.A., Polehovsky Y.S. Shungite amorphous carbon - the natural environment of fullerene // Technical Physics Letters. 2000. V. 26. № 15. P. 689-693.
  13. Antonov A. Research of the nonequilibrium processes in the area in allocated systems. Diss. thesis doctor of physical sciences. Sofia: Blagoevgrad. 2005. P. 1-255.
  14. Ignatov I., Mosin O.V. Structural mathematical models describing water clusters // Journal of Mathematical Theory and Modeling. 2013. V. 3. № 11. P. 72-87.
  15. Ignatov I. Energy Biomedicine / Ed. I. Ignatov. Sofia: Gea-Libris. 2005.
  16. Ignatov I. Water in human body is informational bearer about longevity / in Conference on the Physics. Chemistry and Biology of Water, Vermont Photonics. USA. 2012.
  17. Luck W., Schiöberg D., Ulrich S. Infared investigation of water structure in desalination membranes // J. Chem. Soc. Faraday Trans. 1980. V. 2. № 76. P. 136-147.
  18. Gorshteyn A.E., Baron N.Y., Syrkina M.L. Adsorption properties of shungites // Izv. Vysshykh Uchebn. Zaved. Khimia i Khim. Technol. 1979. V. 22. № 6. P. 711-715 [in Russian].
  19. Cascarini de Torre L.E., Fertitta A.E., Flores E.S., Llanos J.L., Bottani E.J. Characterization of shungite by physical adsorption of gases // J. Argent. Chem. Soc. 2004. V. 92. № 4-6. P. 51-58.
  20. Mosin O.V., Ignatov I. The structure and composition of natural carbonaceous fullerene containing mineral shungite // International Journal of Advanced Scientific and Technical Research. 2013. V. 6. № 11-12. P. 9-21.
  21. Mosin O.V., Ignatov I. The Composition and structural properties of fullerene natural mineral shungite // Nanoengineering. 2012. V. 18. № 12. P. 17-24 [in Russian].
  22. Podchaynov S.F. Mineral zeolite - a multiplier of useful properties shungite. Shungites and human safety / in Proceedings of the First All-Russian scientific-practical conference (3-5 October 2006) / Ed. J.K Kalinin. Petrozavodsk: Karelian Research Centre of Russian Academy of Sciences. 2007. P. 6-74 [in Russian].