Opal matrix with filling interspherical spacing rar-earth manganite - metamaterial for electronics

M.I. Samoylovich; A.F. Belyanin; A.S. Bagdasarian; A.B. Rinkevich; S.A. Bagdasarian; V. Bovtun

Opal matrix with filling interspherical spacing rar-earth manganite - metamaterial for electronics

M.I. Samoylovich¹, A.F. Belyanin², A.S. Bagdasarian³, A.B. Rinkevich⁴, S.A. Bagdasarian⁵, V. Bovtun⁶

research article Pages: 42-50

¹ Dr. Sc. (Phys.-Math.), Professor, Head of Department, Central Research Technological Institute «Technomash» (Moscow)
² Dr. Sc. (Eng.), Professor, Main Research Scientist, Central Research Technological Institute «Technomash» (Moscow)
³ Dr. Sc. (Eng.), Professor, Main Research Scientist, Kotel\'nikov IRE of RAS (Moscow)
⁴ Dr. Sc. (Phys.-Math.), Professor, Deputy Director, Metal Physics Institute of RSA Ural Division (Ekaterinburgh)
⁵ Ph. D. (Eng.), General Director, JSC «Scientific Engineering Center «Technological Developments of Telecommunication and Radio Frequency Identification» (Moscow)
⁶ Dr. Sc. (Phys.-Math.), Leading Research Scientist, Institute of Physics ASCR (Praha)

Keywords: nanocomposites opal matrix rare-earth manganite X-ray diffractometry Raman spectroscopy magnetic and dielectric properties

Abstract

The conditions for the formation of nanocomposites based on the basis of lattice packings SiO2 nanospheres (opal matrices) with included clusters of crystalline phase of of rare-earth manganites of the general formula RMnO3 or RMn2O5, where R - Er, Gd, La, Nd, Tb, Y and Yb in interspherical nanospacing are considered. The composition and structure of the nanocomposites studied electron microscopy, X-ray diffraction and Raman spectroscopy. Results of measuring magnetic, magnetic-resonance and dielectric characteristics of the obtained nanostructures are viewed.

How to cite

Самойлович М.И., Белянин А.Ф., Багдасарян А.С., Ринкевич А.Б., Багдасарян С.А., Бовтун В. Опаловые матрицы с заполнением межсферических полостей манганитами редкоземельных элементов - метаматериал для электронной техники // Наукоемкие технологии. 2015. № 11. С. 42–50.

References

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Hill N.A. Why are there so few magnetic ferroelectrics? // The journal of physical chemistry B. 2000. V. 104 (29). P. 6694−6709.
Inomata A., Kohn K. Pyroelectric effect and possible ferroelectric transition of helimagnetic GdMn2O5, TbMn2O5 and YMn2O5 // Journal of physics condensed matter. 1996. V. 8. № 15. P. 2673−2678.
Sarychev A.K., Shalaev V.M. Electrodynamics of metamaterials. World Scientific and Imperial College Press. 2007. 200 p.
Kong J.A. Electromagnetic wave interaction with stratified negative isotropic media // Progress In Electromagnetics Research, PIER. 2002. V. 35. P. 1−52.
Samojjlovich M.I., Rinkevich A.B., Bovtun V., Beljanin A.F., Nuzhnyjj D., Kempa M., Kleshheva S.M. SVCH-kharakteristiki, mikrovolnovaja provodimost i diehlektricheskie svojjstva nanokompozitov na osnove opalovykh matric s zapolneniem mezhsfericheskikh nanopolostejj metallami // Nanoinzhenerija. 2012. № 3. S. 22−30.
Rinkevich A., Samoylovich M., Belyanin A., Bagdasaryan A.Magnetic metamaterials as perspective materials of radio-electronics // Computational problems of electrical engineering. 2013. V. 2. № 2. P. 85−92.
Bagdasarian A., Samoylovich M., Mkrtchyan Al., Rinkevich A., Belyanin A., Bagdasarian S., Mkrtchyan Ar., Afanasieva A. Technology of synthesis of opal matrix metamaterials // Advanced Materials Research. 2015. V. 1084. P. 58−60.
Bagdasarian A., Samoylovich M., Mkrtchyan Al., Rinkevich A., Belyanin A., Bagdasarian S., Mkrtchyan Ar., Vasilevskaya N. UHF-properties of nanocomposites: magnetic resonance // Advanced Materials Research. 2015. V. 1084. P. 66−71.
Rinkevich A.B., Ustinov V.V., Samojjlovich M.I., Beljanin A.F., Kleshheva S.M., Kuznecov E.A. Nanokompozity na osnove opalovykh matric s 3D-strukturojj, obrazovannojj magnitnymi nanochasticami // Tekhnologija i konstruirovanie v ehlektronnojj apparature. 2008. № 4. S. 55−63.
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Rinkevich A.B., Perov D.V., Samojjlovich M.I., Beljanin A.F., Pashhenko P.V., Timofeev M.A. Opalovye matricy so sloistojj strukturojj Co/Ir i 3D-nanokompozity opalovaja matrica - soedinenija Co // Inzhenernaja fizika. 2009. № 10. S. 18−24.
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Samojjlovich M.I., Bovtun V., Rinkevich A.B., Beljanin A.F., Kleshheva S.M., Kempa M., Nuzhnyjj D. Prostranstvenno-neodnorodnye materialy na osnove reshetchatykh upakovok nanosfer SiO2 // Inzhenernaja fizika. 2010. № 6. S. 29−38.
Samojjlovich M.I., Beljanin A.F., Kleshheva S.M. Fazovye prevrashhenija kremnezema v mezhsfericheskikh nanopolostjakh opalovykh matric // Rossijjskijj khimicheskijj zhurnal. 2012. T. LVI. № 3−4. S. 155−162.
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[1] Kimura T., Goto T., Shintani H., Ishizaka K., Amira T., Tokura Y. Magnetic control of ferroelectric polarization // Nature. 2003. V. 426. P. 55−58.

[2] Hill N.A. Why are there so few magnetic ferroelectrics? // The journal of physical chemistry B. 2000. V. 104 (29). P. 6694−6709.

[3] Inomata A., Kohn K. Pyroelectric effect and possible ferroelectric transition of helimagnetic GdMn2O5, TbMn2O5 and YMn2O5 // Journal of physics condensed matter. 1996. V. 8. № 15. P. 2673−2678.

[4] Sarychev A.K., Shalaev V.M. Electrodynamics of metamaterials. World Scientific and Imperial College Press. 2007. 200 p.

[5] Kong J.A. Electromagnetic wave interaction with stratified negative isotropic media // Progress In Electromagnetics Research, PIER. 2002. V. 35. P. 1−52.

[6] Samojjlovich M.I., Rinkevich A.B., Bovtun V., Beljanin A.F., Nuzhnyjj D., Kempa M., Kleshheva S.M. SVCH-kharakteristiki, mikrovolnovaja provodimost i diehlektricheskie svojjstva nanokompozitov na osnove opalovykh matric s zapolneniem mezhsfericheskikh nanopolostejj metallami // Nanoinzhenerija. 2012. № 3. S. 22−30.

[7] Rinkevich A., Samoylovich M., Belyanin A., Bagdasaryan A.Magnetic metamaterials as perspective materials of radio-electronics // Computational problems of electrical engineering. 2013. V. 2. № 2. P. 85−92.

[8] Bagdasarian A., Samoylovich M., Mkrtchyan Al., Rinkevich A., Belyanin A., Bagdasarian S., Mkrtchyan Ar., Afanasieva A. Technology of synthesis of opal matrix metamaterials // Advanced Materials Research. 2015. V. 1084. P. 58−60.

[9] Bagdasarian A., Samoylovich M., Mkrtchyan Al., Rinkevich A., Belyanin A., Bagdasarian S., Mkrtchyan Ar., Vasilevskaya N. UHF-properties of nanocomposites: magnetic resonance // Advanced Materials Research. 2015. V. 1084. P. 66−71.

[10] Rinkevich A.B., Ustinov V.V., Samojjlovich M.I., Beljanin A.F., Kleshheva S.M., Kuznecov E.A. Nanokompozity na osnove opalovykh matric s 3D-strukturojj, obrazovannojj magnitnymi nanochasticami // Tekhnologija i konstruirovanie v ehlektronnojj apparature. 2008. № 4. S. 55−63.

[11] Rinkevich A.B., Burkhanov A.M., Samojjlovich M.I., Beljanin A.F., Kleshheva S.M., Kuznecov E.A. 3D-nanokompozitnye metallodiehlektricheskie materialy na osnove opalovykh matric // Rossijjskijj khimicheskijj zhurnal. 2012. T. LVI. № 1−2. S. 26−35.

[12] Rinkevich A.B., Perov D.V., Samojjlovich M.I., Beljanin A.F., Pashhenko P.V., Timofeev M.A. Opalovye matricy so sloistojj strukturojj Co/Ir i 3D-nanokompozity opalovaja matrica - soedinenija Co // Inzhenernaja fizika. 2009. № 10. S. 18−24.

[13] Belov N.V. Struktura ionnykh kristallov i metallicheskikh faz. M. Izd. AN SSSR. 1947. 237 s.

[14] Samojjlovich M.I., Bovtun V., Rinkevich A.B., Beljanin A.F., Kleshheva S.M., Kempa M., Nuzhnyjj D. Prostranstvenno-neodnorodnye materialy na osnove reshetchatykh upakovok nanosfer SiO2 // Inzhenernaja fizika. 2010. № 6. S. 29−38.

[15] Samojjlovich M.I., Beljanin A.F., Kleshheva S.M. Fazovye prevrashhenija kremnezema v mezhsfericheskikh nanopolostjakh opalovykh matric // Rossijjskijj khimicheskijj zhurnal. 2012. T. LVI. № 3−4. S. 155−162.

[16] Samojjlovich M.I., Beljanin A.F., Bagdasarjan A.S., Rinkevich A.B., Bagdasarjan S.A., Bovtun V., Kempa M., Nuzhnyjj D., Savinov M. Stroenie i fizicheskie svojjstva nanokompozitov: opalovye matricy - manganity redkozemelnykh ehlementov // Naukoemkie tekhnologii. 2015. T. 16. № 7. S. 75−84.

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