Phenomenological approach to mathematical analysis of the electron spectra of organic semiconductors
- 1 д.х.н., профессор, Башкирский государственный университет, Физико-технический Институт (г. Уфа)
- 2 к.х.н., доцент, Уфимский государственный нефтяной технический университет
- 3 аспирант, Уфимский государственный университет экономики и сервиса
Abstract
In this work, the spectrum of molecules in organic semiconductors is considered as a random process excitations of strongly correlated states. Therefore, the energy spectrum of a molecule is represented using the autocorrelation function, transitions frequency. To calculate the probability of electronic transitions in the UV region is entered relative the empirical autocorrelation parameter μ, which is equal to the ratio of the energy spectrum in the UV region to the energy of the whole electronic spectrum. A correlative relation between the ionization potential (electron affinity) and the parameter μ of polycyclic aromatic hydrocarbons.
How to cite
Доломатов М.Ю., Ковалева Э.А., Паймурзина Н.Х. Феноменологический подход к математическому анализу электронных спектров органических полупроводников // Нанотехнологии: разработка, применение - XXI век. 2016. № 4. С. 43–48.
References
- Ryoji Mitsuhashi, Yuta Suzuki, Yamanari Yusuke, Mitamura Hiroki, Kambe Takashi, Ikeda Naoshi, Okamoto Hideki, Fujiwara Akihiko, Yamaji Minoru, Kawasaki Naoko, Maniwa Yutaka, Kubozono Yoshihiro, Mitsuhashi Ryoji, Suzuki Yuta. Superconductivity in alkali-metal-doped picene // Nature. 2010. V. 464. P. 76-79.
- Gurvich L.V., Karachevcev G.V., Kondratev V.N., Lebedev JU.A., Medvedev V.A. i dr. EHnergii razryva khimicheskikh svjazejj. Potencialy ionizacii i srodstvo k ehlektronu. M.: Nauka. 1974. 351s.
- Eljashevich M.A. Atomnaja i molekuljarnaja spektroskopija. Izd. 2-e. M.: EHditorial URSS. 2001. 896 s.
- Dolomatov M.JU. KHimicheskaja fizika mnogokomponentnykh sistem. CH. 1. Fiziko-khimicheskaja teorija slozhnykh organicheskikh i neftekhimicheskikh sistem. Ufa: In-t problem neftepererabotki i neftekhimii AN RB, Ufimsk. tekhnol. in-t servisa. 2000. 124 s.
- Dolomatov M.JU., Kovaleva EH.A. Novyjj molekuljarnyjj deskriptor modeli «struktura-svojjstvo» dlja ocenki potencialov ionizacii nafto- i antrakhinonov // ZHurnal strukturnojj khimii. 2015. T. 56. № 5. S. 887-893.
- Dolomatov M.JU., Kovaleva EH.A. Novyjj molekuljarnyjj deskriptor dlja prognoza sostojanijj molekuljarnykh sistem // EHlektrotekhnicheskie i informacionnye kompleksy i sistemy. 2015. T. 11. № 2. S. 98-104.
- Klar EH. Policiklicheskie uglevodorody. M.: KHimija. 1971. T. 2. 456 s.
- Stepanov N.F. Kvantovaja mekhanika i kvantovaja khimija. M.: Mir. 2001. 519 s.
- Sosulin JU.G., Kostrov V.V., Parshin JU.N. Ocenochno-korreljacionnaja obrabotka signalov i kompensacija pomekh. M.: Radiotekhnika. 2014. 632 s.
- Perov A.I. Statisticheskaja teorija radiotekhnicheskikh sistem. M.: Radiotekhnika. 2003.