350 rub
Journal Science Intensive Technologies №4 for 2013 г.
Article in number:
Dependence of EPR spectrum SFS parameter on Mn(II) concentration in water solutions
Keywords: EPR electron paramagnetic resonance ESR electron spin resonance SFS superfine structure superfine interaction M.p. Mishchenko\'s point intermediate Mishchenko\'s point
Authors:
D.A. Tanasjuk, A.A. Revina, V.I. Ermakov
Abstract:
It is shown that the form of Mn(II) EPR SFS dependence upon Mn(II) concentration may be approximated by ab initio formula in wide range of concentrations. Electron paramagnetic resonance spectrum superfine structure of Mn(II) water solutions have a special feature at intermediate Mishchenko\'s point.
Pages: 52-57
References
  1. Sergeev G.B.Nanokhimija. M.: Izd-vo MGU. 2003.
  2. Egorova E.M., Revina A.A. Opticheskie svojjstva i razmery nanochastic serebra v micelljarnykh rastvorakh // Kolloidnyjj zhurnal. 2002. T. 64. № 3. S. 334-345.
  3. Dokuchaev A.G., Mjasoedova T.G., Revina A.A. Izuchenie vlijanija razlichnykh faktorov na obrazovanie agregatov serebra v obratnykh micellakh pod dejjstviem γ-izluchenija // KHVEH. 1997. T. 31. № 5. S. 353-356.
  4. Tun CH.M., Tanasjuk D.A., Revina A.A., Ermakov V.I. Opredelenie ehffektivnojj koncentracii marganca v obratnomicelljarnykh sistemakh metodom EHPR // Uspekhi v khimii i khimicheskojj tekhnologii. 2010. T. 24. № 7.
  5. Bljumenfeld L.A., Voevodskijj V.V., Semenov A.G. Primenenie ehlektronnogo paramagnitnogo rezonansa v khimii. Novosibirsk: Izd-vo Sibirskogo otd. AN SSSR. 1962.
  6. Altshuler S.A., Kozyrev B.M. EHlektronnyjj paramagnitnyjj rezonans soedinenijj ehlementov promezhutochnykh grupp. M.: Nauka. Gl. red. fiz.-mat. lit. 1972.
  7. Ermakov V.I.Issledovanie rastvorov ehlektrolitov metodami ehlektricheskojj, magnitnojj relaksacijj i radiospektroskopii // Diss. ... d.kh.n. MKHTI im. D.I. Mendeleeva. M. 1976.
  8. Vertc Dzh., Bolton Dzh. Teorija i prakticheskie prilozhenija metoda EHPR. M.: Mir. 1975.