350 rub
Journal №4 for 2013 г.
Article in number:
Synthesis and investigation of colloidal solutions of magnetite nanoparticles
Authors:
K.G. Gareev - Post-graduate Student, Saint-Petersburg State Electrotechnical University «LETI» n. a. V. I. Ulyanov (Lenin)
I.E. Kononova - Research Scientist, Saint-Petersburg State Electrotechnical University «LETI» n. a. V. I. Ulyanov (Lenin)
V.A. Moshnikov - Dr.Sc. (Phys.-Math.), Professor, Saint-Petersburg State Electrotechnical University «LETI» n. a. V. I. Ulyanov (Lenin)
Abstract:
The article studies colloids of magnetic nanoparticles obtained by depositing a layer of magnetite onto nanostructured sol-gel silica. An investigation of the layers was performed by atomic force microscopy and X-ray analysis. SiO2 fine powder was analyzed by thermal desorption for determining specific surface area. On the basis of microscopy data particle size distribution was estimated. The study showed the possibility tosynthesize aggregative stable aqueous colloidal solutions of Fe3O4/SiO2nanoparticles. Under the influence of external factors, in particular a constant magnetic field induction of more than 10 mTa formation of linear aggregates of particles elongated along the field lines is observed. It was revealed that in the presence of 1 mT magnetic field fractal aggregates were formed, whose growth based on the model of diffusion- limited aggregation of naturally occurring concurrently with the random nature of the cluster-cluster aggregation. The article describes the effect of the concentration of tetraethoxysilane on the value of the specific surface area of silica. When the content of TEOS is in 60-80 % range SiO2 powders are characterized by maximum SSA. Calculating of SiO2 mean particle size from these data yields a value of about 50 nm at 40 vol. % and less TEOS, and more than 100 nm at 90 vol. % , which is consistent with the results of atomic force microscopy.
Pages: 30-36
References

  1. Taketomi S., Tikadzumi S. Magnitny'e zhidkosti. M.: Mir. 1993. 272 s.
  2. Rinkk P. A. Magnitny'j rezonans v mediczine. Osnovnoj uchebnik Evropejskogo Foruma po magnitnomu rezonansu / Pod red. V.E. Siniczy'na. M.: «GE'OTAR-MED». 2003. 256 s.
  3. Bogachev Ju. V., Marchenko Ja. Ju., Nikolaev B. P. Issledovaniya JaMR kontrastiruyushhix svojstv superparamagnitny'x nanochasticz oksida zheleza // Izvestiya Sankt-Peterburgskogo gosudarstvennogo e'lektrotexnicheskogo universiteta «LE'TI». 2012. № 2. S. 10-15.
  4. Voyuczkij S. S. Kurs kolloidnoj ximii. 2-e izd. M.: «Ximiya». 1975. 512 s.
  5. Brinker C. J., Scherer G. W. Sol-Gel Science. The Physics and Chemistry of Sol-Gel Processing. San Diego: Academic Press, 1990. 908 r.
  6. Handbook of sol-gel science and technology: processing, characterization, and applications / Ed. Sumio Sakka. New York, 2004. V. 1-3.
  7. Shabanova N. A., Popov V. V., Sarkisov P. D. Ximiya i texnologiya nanodispersny'x oksidov. Ucheb. posobie. M.: IKC «Akademkniga». 2006. 309 s.
  8. Vorotilov K. A., Sigov A. S., Yanovskaya M. I., Turevskaya E. P. Sol-gel derived ferroelectric thin films avenues for control of microstructural and electric properties // Journal of sol-gel science and technology. 1999. V. 16, № 1-2. P. 109-118.
  9. Vasil'ev V. A., Seregin D. S., Vorotilov K. A. Nanoporisty'e silikatny'e plenki, sformirovanny'e zol'-gel' metodom // Nanomaterialy' i nanostruktury' ? XXI vek. 2011. T. 2. S. 34-42.
  10. Moshnikov V.A., Tairov Ju.M., Xamova T.V., Shilova O.A. Zol'-gel' texnologiya mikro- i nanokompozitov / Pod red. O.A. Shilovoj. Izd-e 1-e. SPb: Izdatel'stvo «Lan'», 2013. 294 s.
  11. Maksimov A.I., Moshnikov V.A., Tairov Ju.M., Shilova O.A Osnovy' zol'-gel' texnologii nanokompozitov /2-e izdanie. SPb: OOO «Texnomedia». Izd-vo «E'lmor», 2008. 225 s.
  12. Gracheva I.E., Moshnikov V.A. Nanomaterialy' s ierarxicheskoj strukturoj por. Ucheb. posobie. SPb.: Izd-vo SPbGE'TU «LE'TI». 2011. 107 s.
  13. Gareev K.G., Matyshkin L.B. Investigation of magnetite suspensions stabilized by porous silica. Proc. of 21st Int. Symp. Nanostructures: Physics and Technology. 2013. P. 121-122.
  14. Bogachev Yu.V., Chernenco Ju.S., Gareev K.G. et al. Study of NMR relaxation in suspensions of magnetite-silica nanocomposites // 10th Int. Symp. Nucl. Magn. Res. in Cond. Mat. Book of Abstracts. 2013. P. 69.
  15. Gareev K.G., Gracheva I. E., Moshnikov V.A. Zol'-gel' texnologii napravlennogo sinteza nanokompozitov na osnove nanorazmerny'x magnitny'x chasticz v porax izoliruyushhej matriczy' // Nano- i mikrosistemnaya texnika. 2013. № 2. S. 9-14.
  16. Gracheva I.E., Moshnikov V.A., Maraeva E.V. et. al. Nanostructured materials obtained under conditions of hierarchical self-assembly and modified by derivative forms of fullerenes // Journal of Non-Crystalline Solids. 2012. V. 358, № 2. P. 433-439.
  17. Gracheva I.E., Olchowik G., Gareev K.G. et. al. Investigations of nanocomposite magnetic materials based on the oxides of iron, nickel, cobalt and silicon dioxide // Journal of Physics and Chemistry of Solids. 2013. V. 74, № 5. P. 656-663.
  18. Moshnikov V. A., Gracheva I. E., An'chkov M. G. Issledovanie svojstv nanomaterialov s ierarxicheskoj strukturoj, poluchenny'x zol'-gel' metodom // Fizika i ximiya stekla. 2011. T. 37, № 5. S. 38-50.
  19. Gracheva I.E., Gareev K.G., Moshnikov V.A. i dr. Issledovanie nanokompoziczionny'x materialov na osnove oksidov e'rbiya i zheleza, poluchenny'x v usloviyax spinodal'nogo raspada i nukleofil'nogo rosta // Fizika i ximiya obrabotki materialov. 2012. № 6. S. 58-64.
  20. Gareev K.G., Gracheva I.E., Kazanczeva N.E. i dr. Issledovanie produktov zol'-gel'-proczessov v mnogokomponentny'x oksidny'x sistemax, protekayushhix s obrazovaniem magnitny'x nanokompozitov // Nano- i mikrosistemnaya texnika. 2012. № 10. S. 5-10.
  21. Gracheva I.E., Moshnikov V.A., Karpova S.S., Maraeva E.V. Net-like structured materials for gas sensors // Journal of Physics: Conference Series. 2011. V. 291, № 1. P. 012-017.
  22. Gareev K.G., Grachev I.E., Al'myashev V.I., Moshnikov V.A. Poluchenie i analiz poroshkov-kserogelej s nanofazoj gematita // Izvestiya Sankt-Peterburgskogo gosudarstvennogo e'lektrotexnicheskogo universiteta «LE'TI». 2011. № 5. S. 26-32.