350 rub
Journal №4 for 2013 г.
Article in number:
Stractural models of water, describing cyclic nanoclusters
Authors:
I.I. Ignatov - Professor, Hannover, Germany
О.V. Моsin - Ph.D. (Chim.), MGUPP
Abstract:
It is informed on last researches of nanostructure of intermolecular water associates (nanoclasters with the general formula (Н2О)n and claster ions [(Н2О)n]+ and [(Н2О)n]- by means of computer modelling and spectroscopy methods 1Н-NMR, IR-spectroscopy, Raman, Kompton dispersion, EXAFS-spectroscopy, diffraction of X-rays and neutrons on water crystals. Theoretical calculations of polihedral nanoclasters (Н2О)n, where n = 3-20 are given. The basic mathematical models describing the structure of water are considered.
Pages: 9-20
References

  1. E'jzenberg L., Kauczman V. Stroenie i svojstva vody'. Leningrad: Gidrometeoizdat. 1975. 431 c.
  2. Pauling L. (ed.) The Nature of the Chemical Bond and the Structure of Molecules and Crystals. New York: Cornell University Press. 1960. 644 p.
  3. Xobza P., Zagradnik R. Mezhmolekulyarny'e kompleksy': Rol' Van-der-vaal'sovy'x sistem v fizicheskoj ximii i biodiscziplinax. Moskva: Nauka. 1989. 376 s.
  4. Bernal Dzh., Fauler R. Struktura vody' i ionny'x rastvorov // Uspexi fizicheskix nauk. 1934. T. 14(5). S. 587-644.
  5. Pimentel Dzh., Mak-Klellan O. Vodorodnaya svyaz', per. s angl., Moskva: Nauka. 1964. 462 s.
  6. Petryanov I.V. Samoe neoby'knovennoe veshhestvo v mire. M: Pedagogika. 1981. 95 s.
  7. Antonov A., Galabova T. Reports from the 6th Nat. Conference of Biomedical Physics and Engineering. Sofia. 1992. 67 p.
  8. Ignatov I., Mosin O.V. Isotopic Composition of Water and its Temperature in Modeling of Primordial Hydrosphere Experiments // Science Review. 2013. № 1. P. 17-27.
  9. Gubin S.P. Ximiya klasterov. M.: Nauka. 1987. 264 s.
  10. Antonchenko V.Ja., Davy'dov N.S., Il'in V.V. Osnovy' fiziki vody'. Kiev: Naukova dumka. 1991. 667 s.
  11. Mosin O.V., Ignatov I. Zagadki ledyany'x kristallov // Soznanie i fizicheskaya real'nost'. 2013. T. 17. № 5. S. 21-31.
  12. Bai J., Wang J., Zeng C. Multiwalled Ice Helixes and Ice Nanotubes // Proc. Natl. Acad. Sci. 2006. V. 3. P. 104-117.
  13. Michaelides A., Morgenstern K. Ice Nanoclusters at Hydrophobic Metal Surfaces // Nat. Mat. 2007. V. 6. P. 597-599.
  14. Timothy S., Zwier S. Chemistry: the Structure of Protonated Water Clusters // Science. 2004. V. 304 (5674). P. 1119-1120.
  15. Pople J.A. Molecular Association in Liquids: A Theory of the Structure of Water // Proceedings of the Royal Society. 1951. V. 205. P. 1081-1089.
  16. Nemuxin A.V. Mnogoobrazie klasterov // Rossijskij ximicheskij zhurnal. 1996. V. 40(2). P. 48-56.
  17. Camojlov O.Ja. Struktura vodny'x rastvorov e'lektroli­tov i gidratacziya ionov. M: AN SSSR. 1957. 180 c.
  18. Henry S., Frank S., Wen-Yang Wen. Ion-solvent interaction. Structural Aspects of Ion-solvent Interaction in Aqueous Solutions: a Suggested Picture of Water Structure // Discuss. Faraday Soc. 1957. V. 24. P. 133-140.
  19. Domrachev G.A., Selivanovsky D.A. The Role of Sound and Liquid Water as Dynamically Unstable Polymer System in Abiogenous Production of Oxygen and the Origin of Life on the Earth. Preprint N 1'90. Gorky: Inst. of Organometallic Chem. of the USSR Acad. Sci. 1990. 20 p.
  20. Antonov A. Research of the Nonequilibrium Processes in the Area in Allocated Systems, Thesis for Awarding of the Degree «Doctor of Physical Sciences». Sofia: Blagoevgrad, 2005. P. 1-255.
  21. Luck W., Schiöberg D., Ulrich S. Infared Iinvestigation of Water Structure in Desalination Membranes // J. Chem. Soc., Faraday Trans. 1980. V. 2. № 76. P. 136-147.
  22. Saykally R. Unified Description of Temperature-Dependent Hydrogen Bond Rearrangements in Liquid Water // PNAS. 2005. V. 102. № 40. P. 14171-14174.
  23. Sykes M. Simulations of RNA Base Pairs in a Nanodroplet Reveal Solvation-Dependent Stability // PNAS. 2007. V. 104. № 30. P. 12336-12340.
  24. Loboda O., Goncharuk V. Theoretical study on icosahedral water clusters // Chemical Physics Letters. 2010. V. 484 (4-6). P. 144-147.
  25. Tokmachev A.M., Tchougreeff A.L., Dronskowski R. Hydrogen-Bond Networks in Water Clusters (H2O)20: An Exhaustive Quantum-Chemical // European Journal of Chemical Physics And Physical Chemistry. 2010. V. 11(2). P. 384-388.
  26. Christie R.A., Jordan K.D. Monte Carlo Simulations of the Finite Temperature Properties of (H2O)6 / in: Theory and Applications of Computational Chemistry: The First 40 Years, A Volume of Technical and Historical Perspectives, Ed. C. E. Dykstra, G. Frenking, K. S. Kim, and G. Scuseria. New York: Theochem, 2005. P. 995-1006.
  27. Choi T.N., Jordan K.D. Application of the SCC-DFTB Method to H+(H2O)6, H+(H2O)21, and H+(H2O)22 // J. Phys. Chem. B. 2010. V. 114. P. 6932-6936.
  28. Zenin C.B., Tyaglov B.V. Gidrofobnaya model' struktury' assocziatov molekul vody' // Zhurnal fizicheskoj ximii. 1994. T. 68(4). P. 636(641.
  29. Keutsch F., Saykally R. Water Clusters: Untangling the Mysteries of the Liquid, One Molecule at a Time // PNAS. 2011. V. 98 (19). P. 105330-10540.
  30. Maheshwary S., Patel N., Sathyamurthy N., Kulkarni A.D., Gadre S.R. Structure and Stability of Water Clusters (H2O)n, n = 8-20: An Ab Initio Investigation // J. Phys. Chem. 2001. V. 105. P. 10525-10537.
  31. Zenin C.V. Strukturirovannoe sostoyanie vody' kak osnova upravleniya povedeniem i bezopasnost'yu zhivy'x sistem, Diss. d.b.n., M: GNC «IMBP», 1999. 207 c.
  32. Chaplin M. The Water Molecule, Liquid Water, Hydrogen Bonds and Water Networks // in: Water The Forgotten Biological Molecule, D. Le Bihan and H. Fukuyama, (eds.), Pan Stanford Publishing Pte. Ltd., Singapore, 2011. P. 3-19.
  33. Cui J., Liu H., Jordan K.D. Theoretical Characterization of the (H2O)21 Cluster: Application of an n-body Decomposition Procedure // J. Phys. Chem. 2006. V. 110. P. 18872-18878.
  34. Mosin O.V., Ignatov I. Struktura vody' i fizicheskaya real'nost' // Soznanie i fizicheskaya real'nost'. 2011. T. 10(1). S. 32-48.
  35. Ignatov I. Energy Biomedicine, Structure of Water. Sofia, Moscow, Munich: Gea-Libris, ICH, 2005. P. 24-48.
  36. Wernet Ph., Nordlund D., Bergmann U., et all. The structure of the first coordination shell in liquid water // Science. 2004. V. 304. P. 995-999.
  37. Tokushima T., Harada Y., Takahashi O., et all. // High resolution X-ray emission spectroscopy of liquid water: The observation of two structural motifs // Chem. Phys. Lett. 2008. V. 460. P. 387-400.
  38. Mosin O.V., Ignatov I. Struktura vody' // Ximiya. 2013. № 1. S. 12-32.