350 rub
Journal №3 for 2013 г.
Article in number:
Modification of carbon nanotubes by low temperature plasma for polymer nanocomposites
Keywords:
сarbon nanotubes and nanofibers
modification by low temperature plasma
set-ups
methods of investigation
polymer nanocomposites
Authors:
A.B. Gilman, M.Yu. Yablokov, A.A. Kuznetsov
Enikolopov Institute of Synthetic Polymer Materials, Russian Academy of Sciences, Moscow, Russia
Enikolopov Institute of Synthetic Polymer Materials, Russian Academy of Sciences, Moscow, Russia
Abstract:
Literature on the modification of carbon nanotubes and nanofibers in a low temperature plasma has been surveyed. Basic techniques for the treatment of nano-objects in discharges of various types and various devices used in these processes have been described. Instrumental methods for the investigation of plasma modified carbon nanotubes and nanofibers and the properties of composites prepared from them with different polymer matrices have been discussed. The modification of carbon nanotubes using low temperature plasma is apparently a promising method that makes it possible both to change the properties of nanotubes and to substantially improve the properties of composite materials that contain them. The plasma treated nanotubes are more uniformly distributed in the bulk of the composite and improve its mechanical and electrical properties.
Pages: 15-27
References
- Rakov E'.G. Ximiya i primenenie uglerodny'x nanotrubok // Uspexi ximii. 2001. T. 70. № 10. S. 934-973.
- Dai L., Mau A.W.H. Controlled Synthesis and Modification of Carbon Nanotubes and C60: Carbon Nanostructures for Advanced Polymeric Composite Materials // Adv. Mater. 2001. V. 13. № 12-13. R. 899-913.
- Breuer O., Sundararaj U. Big Returns from Small Fibers: A review of polymer/carbon nanotube composites // Polym. Composites. 2004. V. 25/ № 6. R. 630-645.
- Coleman J.N., Khan U., Gun-ko Yu. Mechanical Reinforcement of Polymers Using Carbon Nanotubes // Adv. Mater. 2006. V. 18. № 6. R. 689-706.
- Eleczkij A.V. Perspektiva primeneniya uglerodny'x nanotrubok // Ros. nanotexnol. 2007. T. 2. № 5-6. S. 6-17.
- Njuguna J., Pielichowski K., Desai S. Properties of Composites with Carbon Nanotubes // Polym. Adv. Technol. 2008. V. 19. № 8. R. 947-960.
- Ciardelli F., Coiai S., Passaglia E., Pucci A., Ruggeri G. Nanocomposites based on polyolefins and functional thermoplastic materials // Polym. Int. 2008. V. 57. № 6. R. 805(836.
- Morgan P. Carbon Fibers and Their Composites. ? London: Taylor & Francis Group., 2005.
- Krueger A. Carbon Nanotubes / in - Carbon Nanomaterials and Nanotechnology?? Weinheim: Wiley-VCH Verlag GmbH &Co., 2010.
- Badamshina E'.R., Gafurova M.P., E'strin Ja.I. Modificzirovanie uglerodny'x nanotrubok i sintez polimerny'x kompozitov s ix uchastiem // Uspexi ximii. 2010. T. 9. № 11. S. 1027-1064.
- Gonzalez-Guerrero A.B., Mendoza E., Pellicer E., Alsina F., Fernandez-Sanchez C., Lechuga L.M. Discriminating the carboxylic groups from the total acidic sites in oxidized multi-wall carbon nanotubes by means of acid-base titration // Chem. Phys. Lett. 2008. V. 462. № 4-6. R. 256-259.
- Osorio A.G., Silveira I.C.L., Bueno V.L., Bergmann C.P. H2SO4/HNO3/HCl - Functionalization and its effect on dispersion of carbon nanotubes in aqueous media // Appl. Surf. Sci. 2008. V. 55. № 5/1. R. 2485-2489.
- Pastine S.J., Okawa D., Kessler B., Polandi M., Lorente M., Zettl A., Frechet J.M. A Facile and Patternable Method for the Surface Modification of Carbon Nanotube Forests Using ,Perfluoroarylazides // J. Am. Chem. Soc. 2008. V. 130. № 13. R. 4238-4240.
- Bae J.H., Shanmugharaj A.A., Noh W. H., Choi W. S., Ryu S.H. Surface chemical functionalized single-walled carbon nanotube with anchored phenol structures: Physical and chemical characterization // Appl. Surf. Sci. 2007. V. 253. № 9. R. 4150-4155.
- Chen G.-X. , Shimizu H. Multiwalled carbon nanotubes grafted with polyhedral oligomeric silsesquioxane and its dispersion in poly(l-lactide) matrix // Polyme. 2008. V. 49. № 4. R. 943-951.
- Kim W.-J., Usrey M.L., Strano M.S. Selective Functionalization and Free Solution Electrophoresis of Single-Walled Carbon Nanotubes: Separate Enrichment of Metallic and Semiconducting SWNT // Chem. Mater. 2007. V. 19. № 7. R. 1571-1576.
- Li J., Tang T., Zhang X., Li S., Li M. Dissolution, characterization and photofunctionalization of carbon nanotubes // Mater. Lett. 2007. V. 61. № 22. R. 4351-4353.
- Tang X., Jiao Q., Cao Y., Zhang P., Liu H., Wu H., Zhou M., Li X., Zhao Y. Reductive Alkylation and Arylation of Single-walled Carbon Nanotubes in Ethylenediamine via Benkeser Reaction // Chem. Lett. 2009. V. 38. № 3. R. 220-221.
- Liu M., Yang Y., Zhu T., Lin Z. A General Approach to Chemical Modification of Single-Walled Carbon Nanotubes with Peroxy Organic Acids and Its Application in Polymer Grafting // J. Phys. Chem. Part C. 2007. V. 111. № 6. R. 2379-2385.
- Kristinin A.V., Xaritonov A.P., Shul'ga Ju.M. i dr. Poluchenie i xarakterizacziya odnoslojny'x ftorirovanny'x uglerodny'x nanotrubok // Ros. nanotexnol. 2009. T. 4. № 1-2. S. 115-131.
- Syrgiannis Z., Hauke F., Rohl J., Hundhausen M., Graupner R., Elemes Y., Hirsch A. Covalent Sidewall Functionalization of SWNTs by Nucleophilic Addition of Lithium Amides // Europ. J. Org. Chem. 2008. V. 2008. № 15. R. 2544-2550.
- Jasuda X. Polimerizacziya v plazme. - M.: Mir, 1987.
- Plasma Deposition, Treatment and Etching of Polymers / Ed. By R. d-Agostino - San Diego: Academic Press, 1990.
- Inagaki N. Plasma Surface Modification and Plasma Polymerization - Lancaster: Technomic. Publ. Co., 1996.
- E'ncziklopediya nizkotemperaturnoj plazmy'. Vvodny'j tom IV. / Pod red. Fortova F.E. ? M.: Nauka, 2000.
- Rinzler A.G., Liu J., Dai H., Nikolaev P., Huffman C.B., Rodriguez-Macias F.J., Boul P.J. Carbon Nanotube Synthesis and Organization // Appl. Phys. A. 1998. V. 66. № 1. R. 29-39.
- Vohrer U., Hegemann D., Oehr C. XPS, AES, and AFM as tools for study of optimized plasma functionalization // Anal. Bioanal. Chem. 2003. V. 375. № 7. R. 929-934.
- Vohrer U., Zschoerper N. Kohlenstoff-Nanoröhren ? Phönix aus der Asche // Vakuum in Forschung und Praxis. 2007. V. 19. № 2. R. 22-30.
- Vohrer U., Zschoerper N., Moller B. Carbon Nanotubes ? A Material rising like a Phoenix // Vakuum in Forschung und Praxis. 2008. V. 20. № S1. R. 38-46.
- Vohrer U., Zschoerper N.P. Koehne Y., Langovski S., Oehr C. Plasma Modification of Carbon Nanotubes and Bucky Papers // Plasma Process. Polym. 2007. V. 4. № 1S. R. S871-S877.
- Potschke P., Zschoerper N.P., Moller B., Vohrer U. Plasma Functionalization of Multiwalled Carbon Nanotube Bucky Papers and the Effect on Properties of Melt-Mixed Composites with Polycarbonate // Macromol. Rapid. Commun. 2009. V. 30. № 21. R. 1828-1833.
- Khare B.N., Meyyappan M., Cassell A.M., Nguye C.V., Han J. Functionalization of Carbon Nanotubes Using Atomic Hydrogen from a Glow Discharge // Nano Letters. 2002. V. 2. № 1. R. 73-77.
- Khare B.N., Meyyappan M., Kralj J., Wilhite P., Sisay M., Imanaka H., Koehne J., Bauschlicher C.W. A glow-discharge approach for functionalization of carbon nanotubes // Appl. Phys. Letters. 2002. V. 81. № 27. R. 5237-5239.
- Khare B.N., Wilhite P., Quinn R.C., Chen B., Schingler R.H., Tran B., Imanaka H., So C.R., Bauschlicher C.W., Meyyappan M. Functionalization of Carbon Nanotubes by Ammonia Glow-Discharge: Experiments and Modeling // J. Phys. Chem. B. 2004. V. 108. № 24. R. 8166-8172.
- Khare B.N., Wilhite P., Meyyappan M. The fluorination of single wall carbon nanotubes using microwave plasma // Nanotechnology. 2004. V. 15. № 11. R. 1650-1654.
- Plank N.O.V., Jiang L., Cheung R. Fluorination of carbon nanotubes in CF4 plasma // Appl. Phys. Letters. 2003. V. 83. № 12. R. 2426-2428.
- Khare B., Wilhite P., Tran B., Teixeira E., Fresquez K., Mvondo D., Bauschlicher C., Meyyappan M. Functionalization of Carbon Nanotubes via Nitrogen Glow Discharge // J. Phys. Chem. 2005. V. 109. № 49. R. 23466-23472.
- Shi D., He P. Surface Modifications of Nanoparticles and Nanotubes by Plasma Polymerization // Rev. Adv. Mater. Sci. 2004. V. 7. № 2. R. 97-107.
- Gao Y., He P., Lian J., Wang L., Qian D., Zhao J., Wang W., Schulz M., Zhang J., Zhou X., Shi D. Improving the Mechanical Properties of Polycarbonate Nanocomposites with Plasma-Modified Carbon Nanofibers // J. Macromol. Sci. B: Physics. 2006. v. 45. № 4. R. 671-679.
- Shi D., Lian J., Wang W., Lin G.K., He P., Dong Z., Wang L.M., Ewing R.C. Luminescent Carbon Nanotubes by Surface Functionalization // Adv. Materials. 2006. V. 18. № 2. R. 189-193.
- Ramos-deValle L.F., Neira-Velazquez M.G., Hernandez-Hernandez E. Surface modification of CNFs via plasma polymerization of styrene monomer and its effect on the properties of PS/CNF nanocomposites // J. Appl. Polym. Sci. 2008. V. 107. № 3. R. 1893-1899.
- Hernandez-Hernandez E., Neira-Velazquez M.G., Mendez-Nonell J., Ramos-deValle L.F. Surface modification of carbon nanofibers via deposition of an ultrathin coating of plasma-polymerized poly(acrylic acid) and its effect on the properties of polyamide 6/CNF nanocomposites // J. Appl. Polym. Sci. 2009. V. 112. № 6. R. 3510-3518.
- Tseng C.H., Wang C.C., Chen C.Y. Polypropylene Fibers Modified by Plasma Treatment for Preparation of Ag Nanoparticles // J. Phys. Chem. B. 2006. V. 110. № 9. R. 4020-4029.
- Chen I.H., Wang C.C., Chen C.Y. Preparation of Carbon Nanotube (CNT) Composites by Polymer Functionalized CNT under Plasma Treatment // Plasma Process. Polym. 2010. V. 7. № 1. R. 59-63.
- Xu L., Fang Z., Song P., Peng M. Surface-initiated graft polymerization on multiwalled carbon nanotubespretreated by corona discharge at atmospheric pressure // Nanoscale. 2010. V. 2. № 3. R. 389-393.
- Chou W.-J., Wang C.-C., Chen C.-Y. Characteristics of polyimide-based nanocomposites containing plasma-modified multi-walled carbon nanotubes // Composites Sci. & Technology. 2008. V. 68. № 10-11. R. 2208-2213.
- Xu L., Fang Z., Song P., Peng M. Functionalization of Carbon Nanotubes by Corona-Discharge Induced Graft Polymerization for the Reinforcement of Epoxy Nanocomposites // Plasma Process. Polym. 2010. V. 7. № 9-10. R. 785-793.
- Kim J.A., Seong D.G., Kang T.J., Young J.R. Effects of surface modification on rheological and mechanical properties of CNT/epoxy composites // Carbon. 2006. V. 44. № 10. R. 1898-1905.
- Shi D., Lian J., He P., Wang L.M., van Ooij W., Schulz M., Liu Y., Mast D. Plasma deposition of Ultrathin polymer films on carbon nanotubes // Appl. Phys. Letters. 2002. V. 81. № 27. R. 5216-5218.
- Shi D., Lian J., He P., Wang L.M., Xiao F., Yang L., Schulz M., Mast D. Plasma coating of carbon nanofibers for enhanced dispersion and interfacial bonding in polymer composites // Appl. Phys. Letters. 2003. V. 83. № 25. R. 5301-5303.
- Gao Y., He P., Lian J., Schulz M., Zhao J., Wang W., Wang X., Zhang J., Zhou X., Shi D. Effects of surface modification, carbon nanofiber concentration, and dispersion time on the mechanical properties of carbon-nanofiber-polycarbonate composites // J. Appl. Polym. Sci. 2007. V. 103. № 6. R. 3792-3797.
- http: //plasmart.en.ec.21.com.
- Wang W.-H., Huang B.-Ch., Wang L.-Sh., Ye D.-Q. Oxidative treatment of multi-wall carbon nanotubes with oxygen dielectric barrier discharge plasma // Surface & Coating Techn. 2011. V. 205. № 21-22. R. 4896-4901.
- Valentini L., Puglia D., Armentano I., Kenny J.M. Sidewall functionalization of single-walled carbon nanotubes through CF4 plasma treatment and subsequent reaction with aliphatic amines // Chem. Phys. Letters. 2005. V. 403. № 4-6. R. 385-389.
- Shi D., Wang S.X., Van Ooij W.J., Wang L.M., Zhao J., Yu Z. Uniform deposition of ultrathin polymer films on the surfaces of Al2O3 nanoparticles by a plasma treatment // Appl. Phys. Letters. 2001. V. 78. № 9. R. 1243-1245.
- Valentini L., Braca E., Kenny J.M., Lozzi L., Santucci S. Fluorinated amorphous carbon thin films: Analysis of the role of the plasma source frequency on the structural and optical properties // J. Vac. Sci. Technol. Part A. 2001. V. 19. № 5. R. 2168-2173.
- Chen Q.M, Dai L., Gao M., Huang S., Mau A. Plasma Activation of Carbon Nanotubes for Chemical Modification // J. Phys. Chem. Part B. 2001. V. 105. № 3. R. 618-622.
- Bubert H., Haiber S., Brandl W., Marginean G., Heintze M., Bruser V. Characterization of the uppermost layer of plasma-treated carbon nanotubes // Diamond & Relat. Mater. 2003. V. 12. № 3-7. R. 811-815.
- Valentini L., Macan J., Armentano I., Mengoli F., Kenny J. Modification of fluorinated single-walled carbon nanotubes with aminosilane molecules // Carbon. 2006. V. 44. № 11. R. 2196-2201.
- Tseng C-H., Wang C-C., Chen C.-Y. Modification of multi-walled carbon nanotubes by plasma treatment and further use as templates for growth of CdS nanocrystals // Nanotechnology. 2006. V. 17. № 22. R. 5602-5612.
- Tseng C-H., Wang C-C., Chen C.-Y. Functionalizing Carbon Nanotubes by Plasma Modification for the Preparation of Covalent-Integrated Epoxy Composites // Chem. of Mater. 2007. V. 19. № 2. R. 308-315.
- Chou W-J., Wang C-C., Chen C-Y. Plasma Activation of Carbon Nanotubes for Epoxy Composites // J. Inorg. Organomet. Polym. 2009. V. 19. № 1. R. 23-27.
- Xu T., Yang J., Liu J., Fu Q. CF4 plasma-induced grafting of fluoropolymer onto multi-walled carbon nanotube powder // Appl. Phys. A: Mater. Sci. & Proc. 2008. V. 90. № 3. R. 431-435.
- Ionescu R., Espinosa E.H., Sotter E., Llobet E., Vilanova X., Correig X., Felten A., Bittercourt C., Van Lier G., Charlier J.-C., Pireaux J.J. Oxygen functionalisation of MWNT and their use as gas sensitive thick-film layers // Sensors & Actuators. B: Chemical. 2006. V. 113. № 1. R. 36-46.
- Liu A., Honma I., Ichihara M., Zhou H. Poly(acrylic acid)-wrapped multi-walled carbon nanotubes composite solubilization in water: definitive spectroscopic properties // Nanotechnology. 2006. V. 17. № 12. R. 2845-2849.
- Jia R., Li X., Wang J., Zhang D., Zhang Y. Shanghai Inst. Technology. Plasma Modified Carbon Nanotubes for Epoxy Composites ? CN 101747667 (A), publ. 23.06.2010.
- Xiong X., Jaberansari L., Busnaina A., Jung Y.-J., Somu S., Upmanyu M. Highly organized single-walled carbon nanotube networks and method of making using template guided fluidicassembly - US 20100183844 (A1), publ. 22.07.2010.
- Slinker K.A., Coulter K., Wei R. Lockheed Corp. Carbon nanotube networks for some applications - EP 2277824 A2 (US 20090496207), publ. 26. 01. 2011.
- Ozerin A.N., Kurkin T.S., Ozerina L.A., Dolmatov V.Ju. Issledovanie struktury' nanoalmazov detonaczionnogo sinteza metodami rentgenovskoj difrakczii // Kristallografiya. 2008. T. 53. № 1. S. 61-68.